[CX4H3][#6] Primary carbon [CX4H2]([#6])[#6] Secondary carbon [CX4H1]([#6])([#6])[#6] Tertiary carbon [CX4]([#6])([#6])([#6])[#6] Quaternary carbon [CX3;$([H2]),$([H1][#6]),$(C([#6])[#6])]=[CX3;$([H2]),$([H1][#6]),$(C([#6])[#6])] Alkene [CX2]#[CX2] Alkyne [CX3]=[CX2]=[CX3] Allene [ClX1][CX4] Alkylchloride [FX1][CX4] Alkylfluoride [BrX1][CX4] Alkylbromide [IX1][CX4] Alkyliodide